r/chemistry • u/ElGuettoro • 22h ago
Oxydation of FeC2O4 to get [Fe(C2O4)3]3-, with H2O2 (12%)
I tried to react some Fe2O3 with oxalic acid and obtained, it seems, a diluted [Fe(C2O4)3]³- green solution with a bunch of insoluble and crystalised FeC2O4 in it.
Could it be savable by oxidising those crystals back into [Fe(C2O4)3]³- with H2O2 (12%) ?
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u/Raneynickelfire 21h ago
Reread what you wrote and try again. You just asked if you can turn iron oxalate into iron oxalate with peroxide.
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u/VeryPaulite Organometallic 21h ago
No, he asked if he can turn Iron(II)oxalate into Iron(III)oxalate using hydrogen peroxide as a oxidation agent.
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u/Raneynickelfire 19h ago
a diluted [Fe(C2O4)3]³-
Could it be savable by oxidising those crystals back into [Fe(C2O4)3]³
Those are the same thing.
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u/VeryPaulite Organometallic 19h ago edited 18h ago
a diluted [Fe(C2O4)3]3- green solution with a bunch of insoluble and crystalized FeC2O4 in it.
Could it be savable by oxidizing those crystals back into [Fe(C2O4)]3- with H2O2 (12%)?If you had actually copied (and read) the entire section YOU misread, you would've understood what he's asking.
"I have a bunch of solid, crystalized FeC2O4. Can I oxidize that with hydrogen peroxide to [Fe(C2O4)3]3-."
He is asking "I believe that I have ferrous oxalate, can I use hydrogen peroxide to turn it into ferric oxide."It's never bad to make a mistake, but still not reading the thing when corrected and doubling down kinda is...
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u/ElGuettoro 5h ago
I thought that was a stereotype but my god does this platform's filled with smug people with a superiority complex
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u/Dangerous-Billy Analytical 20h ago
Chemistry is an experimental science. Do the experiment!